By Francis A. Carey
The two-part, 5th version of complex natural Chemistry has been considerably revised and reorganized for larger readability. the cloth has been up to date to mirror advances within the box because the past version, particularly in computational chemistry. half B describes the main common and worthy man made reactions, equipped at the foundation of response kind. it could stand-alone; jointly, with half A: constitution and Mechanisms, the 2 volumes offer a entire origin for the research in natural chemistry. significant other web pages supply electronic versions for college kids and workout suggestions for instructors.
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Extra info for Part B: Reactions and Synthesis
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33 with the amine substituents. 9. THE NITROGEN ANALOGS OF ENOLS AND ENOLATE8-ENAMINES AND IMINE ANIONS steric /repulsion N H&H,i;H c,H ~ H 7 Because of the predominance of the less substituted enamine, alkylations occur primarily at the less substituted ct carbon. Synthetic advantage can be taken of this selectivity to prepare 2,6-disubstituted cyclohexanones. The irninium ions resulting from C-alkylation are hydrolyzed in the workup procedure. Ref. 69 Alkylation of enamines requires relatively reactive alkylating agents for good results.
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